Bonus Round: Take Pictures of Things Other Than Spider-Man!

This is an obvious one, perhaps, but worth noting: you don’t always have to take pictures of Spider-Man, even when the game’s called Marvel’s Spider-Man 2. There’s no actual J. Jonah Jameson hovering around your shoulder. There are multiple scenes in the game where your perspective swaps to characters that aren’t Peter or Miles, either during the main story or in side missions, so take the opportunity to shoot a subject you don’t always get a chance to.
And even when you are playing as Peter or Miles? Turn off hero visibility in Camera Mode, or literally turn the camera away from them sometimes. Capturing anything from a fearsome foe to a lavish city vista is just as fun as taking a shot of your shiny superheroes.